An aliphatic-amine-bearing chromatographic support, based on commercial silica, was prepared and tested as potential matrix for affinity immobilization of a copper/topaquinone-containing amine oxidase from lentil seedlings. The support proved to be noticeably effective in immobilizing the enzyme with concomitant purification and activity retention. The immobilization yields and some properties of this preparation were also determined and compared with those of the soluble enzyme. High activity r...
Autori: Barbara Noli, Enrico Sanjust, Francesca Sollai, Giovanni Floris
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25108

<!--[if !supportEmptyParas]--> The photocatalytic degradation of Alcian Blue 8 GX, a copper phthalocyanine cationic dye, has been investigated in aqueous solutions both in heterogeneous and homogeneous systems. Initial colour removal rates in different conditions were calculated in both cases. Influence of amounts of H2O2 and FeCl3 was studied and compared for the two photocatalytic systems. Finally, some conclusions regarding the efficiency of the two photocatalytic processes were es...
Autori: Anca Florentina Caliman, Chrysanthi Berberidou, , Liliana Lazar, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25114

Iinclude urmatoarele articole:� Process water of papermaking: model building and characterization� Landfill inventory in the Republic of Moldova: problems and solutions� Floodplain revegetation and river basin restoration� Environmental problems of copper complex in Bor area� Researches on air micro flora determination from public indoor spaces and hospital wards in an urban area� Current practice of solid waste management in Malaysia and its disposal� An assessment of potential he...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25199

AbstractThe paper discusses some environmental problems caused by the presence of the copper mining and processing complex in the Bor area (Eastern Serbia). The Bor area is a serious hot spot in Serbia. Unsupervised operation of the mining company RTB Bor, without any protective measures, has led to extreme pollution of the Bor River, the Danube and underground waters, soil pollution with heavy metals, air-pollution with sulfur-dioxide etc. Recommendations are suggested as follows: a sustainable...
Autori: Slavka Zeković
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25137

The amperometric response in dynamic or fixed potential conditions, as cyclic voltammetry (CV) and chronoamperometry (CA) of a copper oxide-copper electrode was studied and proposed for the fast characterization of the simulated wastewaters containing acetylsalicylic acid (ASA) and sulfur compounds, i.e., thioacetamide (TA) as organic pollutant models. The additivity of the individual amperometric signals in the overall response of the electrode for mixed solutions corresponded to over 95% recov...
Autori: Aniela Pop, Ciprian Radovan, Florica Manea, Georgeta Burtica, Ilie Vlaicu, Joop Schoonman, Marcel Morariu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25158

Contain all the articles from this issueICEEM /02 PLENARY SESSION:"Environmental Engineering and Management in the Context of Sustainable Development"Design for sustainability (D4S): towards advanced product conceptsHan Brezet, Sacha SilvesterICEEM/02 - ENVIRONMENTAL ENGINEERING SECTION"Water and Wastewater Treatment Technologies"Complex approach to the problem of persistent organic pollutants degradation in water environmentVictor Covaliov, Olga Covaliova, Angela Cincilei, Gilles Mailhot, Pasca...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25176

Include urmatoarele articole:� Keynote Lectures Energy from municipal solid waste: large-scale incineration or small-scale pyrolysis?� Electrical properties of SnO2-Pt/Al2O3 in reduction atmosphere� Corporate management tools to address sustainability Challenges. A reflection on the progress and difficulties experienced during the last decade� Emerging academic responsibilities and opportunities for promoting regional sustainability� Challenges for integrated water resources management...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25200

AbstractIn this paper, the application of the heterogeneous photocatalysis in degradation of a cationic copper phtalocyanine dye, used as model of persistent organic compound is investigated by assessing the efficiency of the process. The influence of hydrogen peroxide on the photocatalytic process is studied using two types of commercial catalysts, such as TiO2 Degussa (88% anatase, 20% rutile) and TiONa Millennium (100% anatase). Another electron acceptor, FeCl3 is also used for investigation ...
Autori: Anca Florentina Caliman, , , Ioannis Poulios, Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25211

AbstractAn assessment of acide drainage forming potential for a mining waste material resulted in a former mine of nonferrous and precious metals ore has been made. The waste material has the following contents: 2,20?ˇ2,28% sulphide sulphur, 2,53?ˇ2,58% Fe, 0,07% Cu, 0,05% Zn, 0,36?ˇ0,40% Pb, 0,008?ˇ0,013% Ca and 3,85?ˇ7,97% sulphate. Bacterial leaching tests in percolating columns during 380 days have been made. The leaching liquor has been recirculated at a liquid:solid ratio of 1L:1kg. After ...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25239

The heavy metal concentrations exceeding the standard admissibility, determine modifications of some cytological parameters. Therefore, by this paper, there were determined the concentrations of copper, iron, manganese and zinc from Prunus persica L. pollen grains (Research-Development Fruitgrowing Station, Constantza, Romania) using wet digestion followed by flame atomic absorption spectrometry (FAAS). Then, the main cytological parameters (such as citological viability and germination capacity...
Autori: Dan Mandalopol, Elena Doroftei, Manuela Rotaru-Stancic, Simona Dobrinas
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25249

AbstractEquilibrium and kinetic studies regarding the sorption of the copper phtalocyanine dye Alcian Blue 8 GX were carried-out within batch experiments. The sorption equilibrium revealed that the pure natural clay can uptake up to 18 mg of Alcian Blue 8 GX per 1 g mass of clay. The cationic dye sorption was best fitted by Freundlich model that is applicable to sorption on heterogeneous surfaces (surfaces with non-equivalent energetic sites). The pseudo-second order kinetic model may be efficie...
Autori: , Maria Gavrilescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25257

AbstractIn Serbia, the more recent sustainable development policy faces a number of serious problems, which are emphasized by the slow pace at which post-socialist r,eforms have been performed. Environmental aspects of transition reforms have hardly been tackled so far, the copper complex in the area of Bor (Eastern Serbia) being a notable example of such a delay. In effect, the practice of a more rigorous and systematic ex ante evaluation of possible future development scenarios is at its very ...
Autori: Miodrag Vujosevic,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25282

AbstractA greenhouse experiment was conducted to determine the phytotoxic effect of heavy metals such as Cd, Cu, Ni, Pb and Zn on the growth of Sunflower (Helianthus annuus): on the seed germination, root/shoot growth and uptake of metals in soil-vermicompost media. The selected metals were dosed at various concentrations ranging from 0, 5, 10, 20, 40 and 50 ppm separately in soil - vermicompost media (3:1) in pot experiment. The seed germination, root and shoot growth were found significantly a...
Autori: Chhotu D. Jadia, Madhusudan H. Fulekar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25306

AbstractThis paper discusses the results of study concerning the interaction between the birch veneer and some compounds with biocide potential action are presented. With this end in view the samples of veneer were immersed in solutions with a concentration of 5% of the following products: unmodified straw lignin or modified through hydroxymethylation, furan resin and tannins dissolved in 0.1 N ammonia solution. To make a comparison, the same combined treatments were applied, using ammonia solut...
Autori: Adina-Mirela Capraru, Elena Ungureanu, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25309

Include urmatoarele articole:� Biomass - A source of chemicals and energy for sustainable development � Equilibrium study of Pb(II) and Hg(II) sorption from aqueous solutions by moss peat� Wood-based epoxy resins and the ramie fiber reinforced composites� Studies on the interaction between birch veneer and compounds with biocide potential action� Effect of methanogenic inhibitors, inocula type, and temperature on biohydrogen production from food components� Energy from biomass in pul...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25313

AbstractPulsed high voltage discharge technology is a newly developed method for knock out viruses in blood with various electrohydraulic discharge reactors. The aim of this study is to investigate the effect of an electrohydraulic discharge treatment system on Hepatitis C virus (HCV) behaviour. The electrohydraulic discharge (EHD) reactor consist of high voltage point discharge electrode above blood surface and cylindrical ground copper electrode containing the blood (in the same time act as th...
Autori: Gamal M. El-Aragi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25362

Include urmatoarele articole:� Environmental Engineering and Management Journal, Vol. 8 Nr. 2� Bioengineering aspects of tissues culture bioreactors for medicine and environmental applications� Removal of bis (1-chloro-2-propyl) ether from wastewater using sonodegradation and biodegradation� A novel plasma reactor for toluene decomposition in contaminated air flow� Study of the copper (II) removal from aqueous solutions by chelating resin Purolite S930 � Analysis of some metal levels...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25371

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25373

â€? Photocatalytic properties of titania - fly ash thin filmsâ€? Study of the viscosity of some biodiesel – diesel oil blendsâ€? Aspects refering to technical and leaching properties of the secondary aluminium slags - cement compositesâ€? Studies regarding phenol and 4-chlorophenol sorption by surfactant modified zeolitesâ€? Cu-Ni nanostructured electrocatalysts obtained by electrocodepositionâ€? Molecularly imprinted poly (vinyl alcohol) films for the selective absorption of glycyrrhizinic ac...
Autori: http://www.ecozone.ro/reviste.php?RID=25374

� Physiological changes in seedling germination and growth plant under chemical stress conditions� Studies on sorption and transport processes of cadmium in soils� Assessment of the anthropogenic impact on water systems by fluorescence spectroscopy� Research on the effects of soil improvement by fertilization on the quality of winter wheat� Halotherapy: From ethnoscience to scientific explanations� Study regarding the sorption of erythrosine from aqueous solution onto soil� Hydroxy...
Autori:
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25375

Abstract The concentrations of some metallic ions (chromium, iron and copper) in Danube River water were determined by molecular absorption spectroscopy. There were studied five sites from Constanta County, in winter, spring and summer of 2008 year. The results can be interpreted having in view the natural and anthropical factors. The highest concentrations of metallic ions, which proved that some of water samples are of 5th quality class, were determined in winter. The quality of Danube Rive...
Autori: Anca Dumbrava,
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25400

Abstract This work examines the influence of experimental conditions on the copper (II) ions removal from aqueous solutions using chelating ion exchange resin Purolite S930. The influence of solution pH, initial metal concentration, contact time, temperature, ionic form of the resin and resin dose was studied in batch experiments. The percent of Cu (II) removal has a maximum at pH 5.0 (buffered solutions), and increases with the increasing of resin dose, of the contact time and of temperature...
Autori: Petru Bulai, Catalin Balan, Doina Bilba, Matei Macoveanu
ISSN: 1582 - 9596
http://www.ecozone.ro/reviste.php?RID=25401

Abstract The studies of Cu (II) adsorption were conducted by testing various sawdust types. Two biomass, oak sawdust wood (Querqus robur) and white poplar sawdust wood (Populus alba), have been compared considering their efficiency for copper removal from diluted water solutions. Raw sawdust proved no efficiency in adsorption. Therefore, pre-treatment processes were developed and optimized, to enhance the sawdust affinity for heavy metals adsorption. The optimized pre-treatment conditions are...
Autori: Dora Lucaci, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25460

Abstract The use of fly ash (FA) in wastewater treatment received a lot of attention for the immobilization of heavy metal cations, mainly Cd2+, Pb2+, Ni2+, Zn2+, Cu2+. For an up-scalable wastewater treatment process, the substrate must have good adsorption efficiency and relatively constant behaviour. Modifying the fly ash surface can be a solution for reaching both goals. The use of FA for heavy metals removal, from wastewaters resulted in the dye finishing industry, faces a supplementary p...
Autori: Maria Visa, Anca Duta
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25471

Abstract In order to improve the photo-efficiency of the electronic process as well as the response into the visible part of the spectrum, TiO2 doping with heavy metal (cadmium, cooper and nickel) have been employed. The objectives of this work are: (a) to prepare doped Me(Cd, Cu, Ni) TiO2 by doctor blade (DB) and spray pyrolysis deposition (SPD) techniques, (b) to characterize the catalysts, (c) to study and compare the activity of the Cd-TiO2, Cu-TiO2 and Ni-TiO2 catalysts on methyl orange ...
Autori: Luminita Andronic, Bianca Hristache, Alexandru Enesca, Anca Duta, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25480

Abstract A simple method to synthesize copper, nickel and Cu-Ni nanotubes in alumina membrane by direct electrochemical deposition technique is presented. This work is divided into three main parts: - elaboration of the nanostructured metals supported on Cu and Ni electroconductive support; - SEM - EDX characterization of nanodeposits; - electrochemical characterization of the nanostructured electrodes; Cu and Cu-Ni nanostructures were obtained by deposition through an alumina membrane (...
Autori: Maria Jitaru, Ana-Maria Toma, Mihaela-Claudia Tertis, Ancuta Trifoi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25496

Abstract The paper presents the results obtained when using thin films (doctor blade) of titanium oxide powder (Degussa P25) and fly ashactivated with NaOH, for advanced treatment of complex waters resulted in the textile industry. There are studied the heavy metal(cadmium, copper) adsorption and the dyes (methyl orange and methylene blue) photo-degradation using these novel substrates.The thin films crystallinity (XRD), morphology and roughness (AFM) were evaluated and no significant changes...
Autori: Anca Duta, Luminita Andronic, Maria Visa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25500

Abstract It were investigated some atmospheric sediments of copper and chromium in mining areas of Dorna Basin by passive monitoring with six species of native epigeic moss (Mnium hornum, Mnium cuspidatum, Mnium punctatum, Polytrichum strictum, Thamnium alopecurum si Cephalozia bicuspidate) in two stages: April - September 2005 and October 2005 - March 2006. Thesedeterminations were achieved in 4 locations: Dealul Boambei, Saru Dornei, Sarisorul Mic, Neagra Sarului. In the same time was deter...
Autori: Catalin Dumitrel Balan, Ionela Mezdrea Cojocareanu Pata, Matei Macoveanu, Sandu-Marius Pata
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25503

Abstract Bioremediation of heavy metal contaminated soil is one of the major concerns of our days. Phytoextraction has been lately utilized as an alternative of in situ remediation technology for polluted soils but is generally perceived to be too slow. Even so, phytoextraction is an efficient long lasting, accessible and environmentally friendly technique. The aim of this paper was to evaluate the phytoextraction potential of bean (Phaseolus vulgaris) in stress conditions induced by heavy me...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25508

Abstract The use of appropriate leaching tests and leaching models can help to predict the hazardous components release from cementbased solidified waste during either utilization or disposal. Numerous parameters influence the leaching rates such as grain size/specimen size,ccc liquid-to-solid ratio, pH value of the leachate, leaching time etc. This study evaluates the effect of initial liquid-to-solid ratio of cement paste on the release of copper from cement-based solidified waste. Dynamic ...
Autori: Constantin Bobirica, Liliana Bobirica, , Ionel Constantinescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25527

Abstract The presence of heavy metals in the environment is a major concern due to their non-biodegradability, bioaccumulation tendency, persistence in nature and toxicity to many life forms. Different treatment techniques for wastewater laden with copper have been developed in recent years to decrease the amount of wastewater produced and to improve the quality of the treated effluent. All techniques have their advantages and limitations in application. One of the most used techniques to rem...
Autori: Petru Bulai, Catalin Balan, Camelia Scripcariu, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25531

Abstract The paper makes qualitative and quantitative analyses of heavy metal contamination of surface waters in Iasi City. The examination of data acquisited from the specific sections of the rivers Bahlui (upstream section, Iasi water treatment plant, Holboca section, downstream section, Iasi water treatment station), Nicolina (quarterly data from the established monitoring system) was performed, based on data provided by the Environmental Protection Agency of Iasi District and Prut Water D...
Autori: Corneliu Horaicu, Florea Cornel Gabrian, Irina Grozavu, Catalin Constantin Calu, Monica Horaicu, Brindusa Robu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25546

Abstract The practical capacity of an ion exchange or chelating resin depends on various process variables, such as initial solution pH, initial metal ion concentration, metal/resin ratio, contact time and temperature. This work presents the optimization of process variables to maximize the copper loading capacity of chelating resin Purolite S930. To study the combined effect of the initial solution pH, initial Cu (II) concentration and resin dosage were used a 23 orthogonal central composi...
Autori: Petru Bulai, Catalin Balan, Corneliu Cojocaru, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25563

Abstract When plants are exposed to heavy metals influence, the processes of growth inhibition, ion leakage of all membrane, distribution of pigment and even more death of plants are produced. The physiological and biochemical changes in germinating seedling and cultivation in plastic pots experiments of different plant species (maize, bean, oat, and spinach) were investigated under the influence of copper ions as stress agent. Differences between tolerances against copper excess in the case ...
Autori: Alina Stingu, Irina Volf, Valentin I. Popa
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25578

Abstract The present paper proposes an integrated-treatment process of leachate from a municipal landfill, which involves two treatment steps. The first step consists in diminishing the organic content through an advanced oxidation process using ozone and hydrogen peroxide. The second step is performed in order to diminish the content of heavy metals through a sorption process on a natural low-cost biosorbent, thus the traces of organic substances remained after oxidative degradation or oxida...
Autori: Carmen Paduraru, Corneliu Pohontu, Igor Creţescu, Lavinia Tofan, Marius Sebastian Secula, Matei Macoveanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25589

Abstract Some samples consisting in silica functionalized in different degrees with dihydroxy-azomethine groups have been tested as sorbents for copper (II) ions from aqueous solutions in different conditions. An indirect monitoring procedure for the complexing process was approached: UV-VIS absorption intensity ? time variation for the metal-containing solution in which complexing silica was soaked. In order to find the conditions in which the maximum efficiency in the metal absorption can b...
Autori: Ciprian-George Piuleac, Maria Cazacu, Silvia Curteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25608

? Environmental Engineering and Management Journal, Vol. 9 Nr. 4 ? THE PROTECTION OF EQUIPMENTS USING VOLATILE INHIBITORS ? CONTINUOUS SURFACE TEMPERATURE MONITORING TO ESTIMATE SENSIBLE HEAT LOSS BY BUILDING FINISHES ? RECYCLE OF POLYAMIDE DYEING WASTEWATER FOLLOWING DECOLORIZATION WITH POLYMERIC SORBENTS ? PERFORMANCE EVALUATION OF AMINO ACID SALT-BASED COMPLEX ABSORBENTS FOR CO2 CAPTURE ? ADSORPTION EQUILIBRIUM STUDIES ON COPPER (II) IONS REMOVAL BY NATURAL WASTE USIN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25666

? HYDROGEL MICROSPHERES BASED ON ENVIRONMENTALLY FRIENDLY POLYMERS WITH POTENTIAL BIOMEDICAL APPLICATIONS ? STUDY ON THE MIXING EFFICIENCY IN A BASKET BIOREACTOR WITH IMMOBILIZED YEASTS CELLS ? MANAGEMENT OF WASTE FROM ELECTRICAL AND ELECTRONIC EQUIPMENT IN CYPRUS ? A CASE STUDY ? SEPARATION AND CHARACTERIZATION OF ANTHOCYANINS BY ANALYTICAL AND ELECTROCHEMICAL METHODS ? AN INTEGRATED DECISION AID FOR IDENTIFYING AND PRIORITIZING STRATEGIES IN FOREST MANAGEMENT ? INFLUEN...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25668

Abstract:Films of CuxS with 430-700 nm thickness were deposited by robotic spray pyrolysis technique, at T = 300Â?C, using 90 sprayingsequences, from water:ethanol:glycerol = 7:2:1 (in volumes) solutions with a molar ratio Cu:S = 1:2.5-3.5. Relative dense,homogenous and uniform films of CuxS (x = 1.8-2), with Eg = 1.97-2.49 eV and exhibiting electric resistance behavior wereobtained. The as-deposited films were annealed in air or in sulfur atmosphere, at 300 Â?C, for one hour. Dense and uniform ...
Autori: Alexandru Enesca, Anca Duta, Ionut Popovici, Luminita Isac
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25749

Abstact:0.5 - 2.0% CuO-doped ZnO (CuO-ZnO) photocatalysts were prepared with a simple mixing method where the oxides wereinitially synthesized through precipitation. The physico-chemical properties of CuO-doped ZnO photocatalysts were studied viaXRD, TEM, XRF and BET method and their photoactivity was evaluated by degrading methyl orange (MO) dye. The propertiesof ZnO were not affected by the addition of CuO except for the particle size of the photocatalyst, which increased proportionallywith Cu...
Autori: Abdul Halim Abdullah, Md. Jelas Haron, Nor Zafirah Razali
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25785

Abstract:This study is focused on the influence of Co and Cu ions located in Zn/Ni/Al matrix on the structural, textural and catalyticproperties of layered double hydroxides (LDHs). The samples were prepared by co-precipitation (Ni2+/Co2+(Cu2+)=0.25;M2+/M3+=2)) at low super-saturation and afterwards characterized by XRD, nitrogen physisorption, thermogravimetry, FT-IR, DRUV-Vis and TPR. The XRD results show that the resulted solids are well crystallized and contain only pure phases of LDHs.Also,...
Autori: Adrian Ungureanu, Alexandru Chirieac, Brindusa Dragoi, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25789

The purpose of this study was to prepare new nanocomposite catalysts of Metal/LDHs type by mild reduction of transition metal cations Co2+ and Cu2+ substituted in the matrix of ZnAl-LDH at 150°C and atmospheric pressure, under hydrogen flow. To this end, a series of ZnCuCoAl layered double hydroxides (LDH) precursors were synthesized by co-precipitation method. M2+/M3+ (i.e., Zn2+/Al3+) molar ratios were kept constant while the Cu2+/Co2+ molar ratios were varied in order to investigate their in...
Autori: Adrian Ungureanu, Alexandra Sasu, Alexandru Chirieac, Alina Moscu Corcodel, Brindusa Dragoi, Constantin Rudolf, Emil Dumitriu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25852

The metal sensitivity and selectivity of two fluorescent proteins was investigated. The studied proteins are mutant forms of the red fluorescent protein (DsRed); according to our results, both proteins showed sensitivity to the presence of copper[II] and nickel ions. The fluorescence intensity of the proteins has decreased significantly in the presence of copper ions in the micromolar range. Metal binding by these proteins is a reversible process, as addition of a chelating agent liberates the b...
Autori: Beata Abraham, Ildiko Miklossy, Judit Petres, Laszlo Szilagyi, Maria Szabo (Palfi), Szabolcs Lanyi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25870

The present study was carried out to highlight the areas where heavy metal content in the soils from Rodna mining perimeter exceeds normal limits and to attempt to reduce the concentration of free heavy metal ions by using natural zeolite from the Dej tuff. In order to emphasize the heavy metal content and their accumulation in soil in Rodna region, 35 soil samples were collected from the upper and deeper layer (about 0-10 and 10-20 cm depth) and analyzed to determine total and free Cu, Pb and Z...
Autori: Ramona Nimirciag
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=25900

AbstractThis paper deals with the experimental investigation related to removal of hydrogen sulfide from simulated groundwater byadsorption/oxidation on activated carbons. Carbonaceous adsorbents were synthesized from peach stones by physical-chemicalactivation method and modified by oxidation following impregnation with Cu2+ by ion-exchange method. Obtained carbonaceousadsorbents were characterized by specific surface area and micropore volume. Surface chemistry properties were evaluated usingB...
Autori: , , Vasile Rusu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26026

AbstractPrinted circuit boards-PCBs are particularly rich in copper and precious metals. Recoveries of metals in our work started withtests for electrodeposition of Au, Ag and Cu from synthetic solutions on graphite and copper electrodes. Processes were studiedusing cyclic voltammetry in ranges: (-1200)-500 mV and (-800)-(-200) mV and (-400)-1400 mV. Different supportingelectrolytes like: H2SO4 0.5M, HCl 0.1M and HNO3 0.1M were used. Electrodeposition of studied metals from real solutions wasfol...
Autori: Adina Căta, Cristian Tănasie, Daniel Boc, Firuţa Fiţigau, Mariana Nela Stefănuţ, Paula Sfîrloagă, Raluca Pop, Zoltan Űrmösi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26036

AbstractThe scope of the present paper is water management dimensioning closed to the copper mining area in the Medet region(Bulgaria). The mining works left an open pit and several waste rock dumps within the catchment area of Medetska River. Atpresent although the flooding of open pit is going on, it will be finished approximately in 2018. Water treatment is necessary dueto the high concentrations of pollutants (sulphate and copper) in the waters influenced by mining. The objective of the stud...
Autori: Gabriela Biali, Petra Schneider, Ralf Löser
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26077

AbstractThe present study reports the efficiency of almond shell as a cheap and available material for the removal of Cu (II) fromcontaminated aqueous solutions. The equilibrium experiments indicated that Cu (II) sorption obeyed the Langmuir isotherm at26, 40 and 55oC. The highest value of the maximum uptake (Qo) from the Langmuir equation was found 6.783 mg g-1 at 40oC.The various thermodynamic parameters such as ΔGo, ΔHo and ΔSo were also calculated. The values of ΔGo varie...
Autori: Soheil Aber
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26080

Abstract Heavy metals are common contaminants of freshwaters and they can produce toxic effects on aquatic fauna and flora. The ions of heavy metals existing in freshwaters are well known as toxicants for the aquatic organisms. Duckweed is an aquatic plant of small size that floats on fresh water surface of lakes and marshes. The small plants are highly exposed to aquatic pollutants and as a result they are very sensitive to the toxic effects. As consequence the duckweed plants are...
Autori: Vasile Oros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26122

AbstractPotential of unmodified Wheat Straw as an adsorbent for the removal of lead and copper was studied. Effect of pH, adsorbentdose, contact time and initial metal concentration on the removal of the metal ions were also investigated. Maximum removal oflead was found to be 43.55% by wheat straw under optimum conditions (pH=5, adsorbent dose=16g/L, contact time= 240minutes, metal concentration=100 mg/L). Unmodified Wheat straw removed 0.381 mg/g of lead. While 56.36% copper removalwas achieve...
Autori: Mehwish Anis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26209

AbstractThis work presents the removal of heavy metal ions (Cu2+ and Cr3+) from aqueous solutions with the use of pine (Pinus silvestris) sawdust. The experiments were conducted in a batch mode. Kinetic and equilibrium parameters of biosorption – which are best described by pseudo-second order and Langmuir models – were determined. The maximum sorption capacity at pH 5 and a temperature of 20°C for pine sawdust amounted to 21.47 mg/g for Cu2+ ions and 39.63 mg/g for Cr3+ ions, respectively.Therm...
Autori: Anna Witek-Krowiak
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26210

AbstractIn this work the adsorption of Cu2+ and Zn2+ from industrial wastewater by peanut shells without any pretreatment wasinvestigated through optimization techniques such as a feed-forward back-propagation artificial neural network and a simplexalgorithm. The Levenberg-Marquardt algorithm was the best back-propagation algorithm, with a minimum mean squared error of0.000217 for Cu(II) and of 0.000229 for Zn2+. Mean square error on the validation set is used as an estimate for variance.Accordi...
Autori: Başak Mesci
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26227

AbstractThe biosorption equilibrium isotherms of copper ions from wastewater onto date stones (DS) and palm-trees Waste (PTW) inaqueous solution over a range of temperatures between 25 and 70°C were studied and modelled. To predict the biosorptionisotherms and to determine the characteristic parameters for process design, five models frequently used in the literature -Langmuir, Freundlich, Temkin, Sips and Redlich-Peterson were applied to experimental data.The Langmuir’s model gives the most acc...
Autori: Fatiha Mechati, Fatima Addoun, Mejdi Jeguirim, Meriem Belhachemi, Zohra Belala
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26319

AbstractStudies about the adsorption behavior of Cu(II) on D151 resin were conducted. Parameters including the effects of pH,temperature, contact time and initial metal ion concentration were studied by batch methods. Results showed that the adsorptionwas strongly dependent on pH of the medium, and the maximum uptake was obtained at pH 6.90. In the batch system, the D151resin exhibited the highest Cu(II) uptake as 277.8 mg/g at 318K, calculated by the Langmuir model. The adsorption kinetics were...
Autori: Caiping Yao, Chunhua Xiong, Xinyi Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26333

AbstractThis paper discusses some environmental problems caused by the mine waste from the Copper Mine Bor in Serbia. The CopperMine Bor and the Smelter generated about 2x109 tones of waste materials, located in the vicinity of the Bor. They cover mining,flotation tailings and smelting slag wastes. The existing mine waste have been formed during a hundred-year-old of mining andmetallurgical activities in Bor. Also, new quantities of wastes (up to ten thousand tones) have been produced daily by u...
Autori: Jovica M. Sokolović, Novica Milosević, Rodoljub D. Stanojlović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26334

AbstractThe main objective of the current research is to determine the content of heavy metals from the Bistrita river banks, respectivelyupstream of Bacau city, Romania, in Bogdan Voda area, and downstream of Bacau city. Because of their bio-accumulationtendency heavy metals can generate a negative impact on soil, as well as on certain physiological and biochemical indicators ofplants and animals metabolism. The selection of sampling points (upstream and downstream of Bacau city) took intoconsi...
Autori: Cristian Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26436

AbstractWater recycling and reuse, answering the needs of creating cleaner water resources, need to be closely related with water resourcemanagement and technologies. Current municipal wastewater treatment plants are capable to control conventional pollutants(carbonaceous compounds, particulate matter, nutrients). Priority organic compounds, like polyaromatic hydrocarbons,polychlorinated biphenyls, endocrine disrupting chemicals, personal care products, pesticides etc., may escape the treatment ...
Autori: Andreea Chelba
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26521

AbstractAtomic absorption spectrophotometry (AAS) technique was applied in order to identify the occurrence of certain heavy metals insamples of pork products, such as bacon, ham, sausage and salami, taken from four commercial centers in Romania. Lead levelsin samples varied from 0.58 to 0.96 mg/kg, Cadmium values from 0.11 to 0.21 mg/ kg, Copper from 0.73 to 1.32 mg/kg, whileZinc levels were detected between 32.19 and 42.12 mg/kg. Lead, Copper and Zinc found in samples were lower than themaximu...
Autori: Gabriel Vasile Hoha
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26522

AbstractHeavy metals in sludge have been one of the limiting factors for sludge reclamation, and therefore the changes of heavy metalsduring sludge treatment process should be concerned. This study investigated the detailed profile of changes of seven typicalheavy metals (As, Cd, Cr, Cu, Ni, Pb, and Hg) in the activated sludge during ultrasonic treatment process. The influences ofsonication time and ultrasonic power density were studied. Results showed that heavy metals in sludge were released i...
Autori: Tian Wan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26563

AbstractThis study aims to understand the acid-leaching behavior of metals from 2 to 4 mm waste printed circuit boards (WPCBs)containing 22.0% ą 1.1 Cu, 6.7% ą 0.2 Ca, 0.68% ą 0.02 Sn, 0.59 ą 0.01 % Pb, 2.71% ą 0.08 Al, 0.22% ą 0.01 Fe, etc..Copper leaching was increased for sulfuric acid concentrations up to 1.2 mol/L and hydrogen peroxide concentrations of 10.0vol% for a pulp density of 100 g/L at 50°C over 4 h, whereas for the same concentrations of sulfuric acid and hydrogen peroxidecopper l...
Autori: Manoj Kumar
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26566

AbstractPresent study was envisaged to study chelators-metal interaction in phytoaccumulation of metals as a bioremediation technologyto decontaminate metal pollution and adsorption of metals on soil. Lactuca sativa was used as model plant for phytoaccumulationto identify uptake of Cadmium (Cd) and Lead (Pb) and their subsequent accumulation in edible tissue of plant. Cadmium andlead were two selected metals for phytoaccumulation and copper was also studied for adsorption experiment. Green house...
Autori: Audil Rashid
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26568

Abstract The present study was conducted to determine the heavy metals (Fe, Mn, Zn, Cu, Pb, and Cd) and essential oils content in the berries of Juniperus phoenicea L. grown in two different geographic origins; Dana conservation and Al-Hisha forest in Jordan. Atomic absorption and Hydrodistillation methods were used to determine heavy metals concentrations and oil contents in plant samples of J. phoenicea L., respectively. Results showed that, the oil yielded from J. phoenicea L. berries in ...
Autori: Mohammad Sanad Abu-darwish
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26595

OPTIMIZATION OF REDUCTION OF COPPER USING Stenotrophomonas maltophilia PD2 BIOMASS AND ARTIFICIAL NEURAL NETWORK MODELING ...
Autori: Arpita Ghosh
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26616

Abstract Samples were collected for six months (nine storm events) to observe the contaminant loads from three highway segments at Rawalpindi, Pakistan. The contaminants analyzed include total suspended solids (TSS), total dissolved solids (TDS), total nitrogen (TN), chemical oxygen demand (COD), total organic carbon (TOC), total phosphorous (TP), sulphate (SO4), chloride (Cl-), iron (Fe), copper (Cu), zinc (Zn), lead (Pb), and chromium (Cr). Mass vs. volume [M (V)] curves were drawn to inve...
Autori: Hamid Iqbal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26617

Abstract Copper nanoparticles were successfully synthesized on polyether-functionalized mesoporous silica to investigate the effect of metal loading (10, 25 and 35 wt. % Cu) on their structural and catalytic properties. The oxide forms of these nanocomposite materials were thoroughly characterized by nitrogen physisorption, SAXS, WAXS, TEM, EDXS, and TPR, whereas the metallic forms were analysed by N2O chemisorption. The results indicated that the mesostructured SBA-15-like hybrids favoured ...
Autori: Constantin Rudolf
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26653

Abstract The capacity of ion exchange resins, MN 500 and C100 H, for the removal of copper ions from aqueous solution has been investigated under different conditions, namely: initial solution pH, initial metal-ion concentration and contact time. The adsorption of Cu(II) on these resins follows the first-order reversible kinetic. The film diffusion of Cu (II) in these ion exchange resins was shown to be the main rate limiting step. The studies showed that these cation exchange resins can be ...
Autori: Cristina Modrogan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26658

Abstract The removal efficiency of algal biomass Chlamydomonas reinhardtii for Pb and Cu metal ions was evaluated in single and binary metal systems. Biosorption experiments were performed in solutions containing 0.2 g L-1 of algal biomass at 30oC and pH 6. Initial metal ion concentrations ranged from 10-7 M to 10-6 M. Thermal analysis of the biosorbent indicated that algal cells are composed of groups containing C, H, N, and S. The presence of ionisable functional groups responsible for bio...
Autori: Roula Flouty
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26709

Abstract The recovery of raw materials from waste represents a sustainable growth opportunity for those countries with limited mineral resources availability. A case study for an integrated approach to recover raw materials from spent fluorescent lamps is presented, with the aim of improving the current treatments which are only able to recover the glass fraction. In particular a hydrometallurgical process was developed to obtain valuable metals such antimony, copper, and rare earths (yttriu...
Autori: Roberta De Carolis
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26782

Abstract This study was aimed to stimulate laccase production by Trametes pubescens MUT 2400 by using a tomato-based medium. Two sequential 2x2 factorial designs were used to determine the effect of carbon (C) and nitrogen (N) source concentration on laccase activity and biomass concentration; copper was used as the sole inducer (0.75 mM). Analysis of the first factorial design showed that N had a strong positive effect on the maximum laccase activity, which occurred at day 12 of cultivation...
Autori: Federica Spina
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26795

Abstract It has been shown that the scale of damage in buildings with steel reinforcement, due to direct lightning strikes, is insignificantly small compared to lightning effects on buildings with no such steel reinforcement. Observed small-scale damages are also confined to points of strike; hence the only risk for occupants and properties is injury or damage caused by falling materials. A large number of such cases have been observed in Sri Lanka and Malaysia. All damaged structures, obser...
Autori: Chandima Gomes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26821

Abstract The paper describes a numerical analysis concerning the behaviour of Cu and Ni based catalysts having different mole ratios of Ni to Cu in the process of glycerol hydrogenolysis. The impregnation technique was used to prepare the copper and nickel based catalysts. Our study revealed that their performances are different and depends on the Ni/Cu ratio. The catalysts were tested using various reaction conditions, such as time and temperature, and their performances analysed based on t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26843

Abstract The aim of this study is to investigate the copper (Cu), nickel (Ni) and chromium (Cr) levels in cultivated black tea in north of Iran. The infusions of Cu, Cr and Ni in tea after 5, 15 and 60 min brewing time were measured. Results showed that the highest (2.32±2.63 mg/kg) and the lowest (2.16±1.84 mg/kg) mean levels of Cu were observed after 15 and 60 min, respectively. The mean levels of Ni and Cr at 60 min were the highest (13.72±8.09 mg/kg and 1.30±1...
Autori: Azita Mohagheghian
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26865

Abstract Parkinson's disease (PD) is a neurodegenerative disorder that occurs due to a progressive degeneration of dopaminergic (DA) neurons. Brain area affected by progressive destruction of neurons controls movements, and patients with PD reveal rigid and uncontrollable gestures, postural instability, small handwriting and tremor. There are some risk factors that have been proven to trigger PD with a certain probability (for example insecticides exposure, and genetic and environmental ...
Autori: Oana Geman
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26868

The work studies the degree of heavy metal pollution in water, sediment and soil in the industrial platform area from Ramnicu Valcea, Romania. The water and sediment samples were collected from three locations of the Olt River, in two distinct periods, February and June 2010. Concentrations of nickel, copper and cadmium were analyzed. The soil samples were collected from eight points and the same elements were analyzed, in the above mentioned interval of time. The results of water and sedime...
Autori: Mihaela Iordache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=26961

This paper presents a mathematical model developed to solve the problem of adequate blending composition for copper smelting process and it is exclusively for the purpose of the case study in "RTB BOR" (Copper Smelter in Bor). The model proposes an objective function, which maximizes the profit by calculating both the “penalties” for the hazardous concentrate elements and “benefits” for the useful ones. Apart from the basic constraints of the existing mathema...
Autori: Ivan Jovanović
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27002

Pain levels may interfere with a patient`s decision when it comes to choosing an appropriate intrauterine system. To our knowledge, there is no study which compares the pain levels during and in the first weeks after the insertion of the levonorgestrel-releasing intrauterine system (LNG-IUS), opposed to copper T380A intrauterine device (C T380A IUD), considering the structural differences between the two devices. In the Department of Obstetrics and Gynecology of University Emergency Hospital...
Autori: Monica Cirstoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27022

The multi-parametric quality index (ICPM) is a dimensionless number used to evaluate the overall water quality and it is a useful tool for policy makers and for the public. This study aims to introduce the ICPM algorithm. The ICPM was developed to assess the water quality of the Lower Danube River using information obtained from the analysis of 41 water quality indicators from a monitoring program during 2011-2014. ICPM used the data for the previous 28 months as reference to evaluate the lat...
Autori: Violeta-Monica Radu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27035

The paper deals with the amounts of total and plant available forms of heavy metals (Pb, Cr and Cu) and relation between soil properties in three catenas in postglacial area of the Łyna River valley, NE Poland. The results were presented on the background of four geochemical landscapes distinguished within the study area: eluvial or trans-eluvial, eluvial accumulative, trans-superaqual and super-aqual. The average total content of heavy metals amounted to: Pb – 14.05 mg kg-1 d.m., ...
Autori: Paweł Sowiński
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27058

This paper reports the potential of rice husk waste biomass to remove copper (II) from simulated wastewater under different experimental conditions. For this, rice husk has been pre–treated by boiling, formaldehyde and concentrated sulphuric acid. Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy and Energy dispersive analysis X–ray analyses were performed before and after adsorption, to explore number and position of the functional groups available for copper ...
Autori: Manjeet Bansal
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27095

A submerged membrane bioreactor (MBR) was applied to treat digested piggery wastewater (DPW). The removal of chemical oxygen demand (COD), ammonium-nitrogen (NH4-N), two kinds of heavy metals and ten kinds of antibiotics were studied. The hydraulic retention time (HRT) was gradually shortened from 12 days to 2.7 days, by which correspondingly the volumetric COD loading rate was increased from 0.4±0.1 to 2.8±0.6 kg /(m3·d) and volumetric NH4-N loading rate was increased fr...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27150

Animal manure is widely used as organic fertilizer for crops. However, high concentrations of heavy metals in animal manure are of great concern. In this study, we found that chicken and pig manure compost contain high concentrations of arsenic (As), cadmium (Cd), copper (Cu) and zinc (Zn), and the concentrations of these heavy metals in the pig manure were higher than those in the chicken manure. Chicken or pig manure compost fertilization elevated the concentrations of these heavy metals in th...
Autori: Guilan Duan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27155

Occurrence of antibiotics and heavy metals, together with concentrations of conventional pollution indicators were assessed in digested piggery wastewater (DPW) generated in ten large-scale pig farms in Jiaxing City, China. Results showed that water quality of DPW varied in different farms as well as in different seasons. Digested piggery wastewater pollution tended to be less serious in Summer than in Spring, Autumn and Winter. Conventional pollution indicators of chemical oxygen demand (COD...
Autori: Rui Liu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27159

Date pits were used as a low-cost adsorbent to study the effective removal of copper (II) ions in an aqueous solution on the basis of adsorption kinetics and isotherm equations. Before and after the adsorption process, the date pits were characterized by electron scanning microscope (ESM) as well as Infrared spectroscopy (IR). The effects of the pH, zero point of charge, the adsorbent mass, and the adsorbent particle size on the adsorption of copper (II) were also studied. Equilibrium data were ...
Autori: Tarek E. Khalil
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27212

In this article we present the results of the study concerning the relationship between the concentration of trace elements (lead, chromium, cadmium, cobalt, copper, zinc and nickel) in soil and in the leaves and bark of Populus nigra L. The samples were collected in the period May 2010 – October 2010 in two areas from the Romanian North Littoral of Black Sea. The concentrations of the trace elements in soil, leaves and bark were determined using Flame Atomic Absorption Spectrometry (F...
Autori: Lucica Barbeş
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27239

Researches and analysis of heavy metals concentrations in the fish species exploited as a food source are of great interest due to long term toxic effects on human health even at very low concentrations. Therefore, we have conducted this study in an area of great interest in terms of aquatic biodiversity, but also of tourism and trade. Depending on the degree of toxicity in delta aquatic ichtyofauna, five heavy metals (Cr, Cu, Hg, Ni, Pb) and a metalloid (As) concentrations were measured in the ...
Autori: Adrian Burada
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27293

The paper aims to present the sorption properties of two sorbent substrates (composts) prepared by aerobic fermentation from vegetables waste composted with beech sawdust (BR2) and beech ash (BC1) to be used for Cu2+ removal from wastewaters. The composts structures and surface properties were characterised in terms of active groups (FTIR), crystallinity (XRD), morphology (SEM), topography (AFM) and specific surface and pores analysis (BET), and the changes in properties after Cu2+ sorption were...
Autori: Ileana Manciulea
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27323

In the current context of industrialization, chemical and radioactive pollution is a concern for environmental protection and interference with human health. Care for environmental protection also includes vegetation that grows spontaneously in potentially contaminated places, thus avoiding illness among the population if consumed. The study area is located at 4.5km SSE from downtown Bacău City, Romania and is the result of the manufacture of H3PO4 through the wet method. In this study, t...
Autori: Mioara Săndulache Rachieru
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27331

The objective of this study was to develop a naturally dyeing process of 70% wool /30% Angora mohair blended yarns by using bio-mordants as an environmentally friendly alternative for the conventional metallic salts. Bio-mordanting operation was achieved by using of condensed tannin extract from quebracho bark trees. Conventional mordanting has been performed using the conventional mordants like copper sulphate and tin chloride. Another specific objective of this study was to investigate the pos...
Autori: Ioana Stanculescu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27337

This paper reports an improved chlorolignin (CL) oxidative decolorization in alkaline media by the use of a heterogeneous system consisting of hydrogen peroxide and a silica [bis(dibenzoylmethido) copper II] (S1) catalyst. The catalytic functions of S1 in the presence of H2O2 were evaluated by comparing the chlorolignin decolorization in media with and without addition of catalyst. Since decolorization is associated with CL degradation, the pH variation and chloride release assays were carrie...
Autori:
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27448

In this study, the adsorption of Cu(II) ions on the uncalcined and calcined nanocrystalline hydroxyapatites was investigated. The nanohydroxyapatites were prepared by wet coprecipitation method and their physicochemical properties were investigated using XRD, BET and SEM-EDX analysis. The uncalcined and calcined hydroxyapatite samples have crystal sizes smaller than 100 nm and a specific surface area of 325 m2/g and 69 m2/g, respectively. The effects of solution pH, adsorbent dose, initial solut...
Autori: Ana Maria Mateiuc
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27464

An experimental design methodology was applied to study the copper removal from aqueous solutions by immobilized nanoscale Lentinus edodes. The effect of the various variables (biomass loading, initial metal ions concentration, PH, contact time, agitation speed and temperature) were studied in the batch experiment. The results showed that pH, contact time and agitation speed were the most significant variables on biosorption of copper ions determined by Minimum Run Equireplicated Res V Design...
Autori: Rong Chen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27487

The aim of the studies was to evaluate the influence of the 30-year operation of a small retention reservoir fed with water from a forest-agricultural catchment area on the contents of selected mineral elements substances in bottom deposits. The studies were carried out in the Łoje dam reservoir (N 53o7’28’’, E 20o48’20’’), supplied by the regulated Łojówka stream. Deposit samples were collected in four transects perpendicular to the reservoir...
Autori: Ireneusz Cymes
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27518

This paper investigates the macrophyte Azolla pinnata modified with sodium hydroxide, as a bioadsorbent for Cu2+ and Pb2+ ions in synthetic solutions. Biomaterial characterization was performed using Scanning Electronic Microscopy (SEM); Energy- Dispersive X-Ray Spectroscopy (EDX); Fourier Transform Infra-red (FTIR) spectroscopy techniques and through the blocking of carboxylic and sulfonic functional groups. Kinetics of the process has highlighted a quick and efficient adsorption, even in low ...
Autori: Arielle Barros
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27532

This paper describes the preparation and use of a low cost biosorbent made of castor leaves for the extraction of Cu(II) from an aqueous medium. The biosorbent was characterized by Fourier transform infrared spectroscopy (FTIR), surface area and pore diameter measurements. The results showed absorption bands of carboxylic and amide groups at 1738 and 1540 cm-1, respectively, and the measured surface area was 1.3728 ± 0.0160 m2 g-1, with predominance of microporous < 10.51 Å. ...
Autori: Milene S. Pereira
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27540

Chemical oxidation of pyrite and chalcopyrite by ferric sulfate (Fe2(SO4)3) solution and biogenic ferric iron obtained by mixed culture of isolated thermotolerant Acidithiobacillus sp. 13Zn and Leptospirilum ferriphilum CC immobilized on natural carriers- zeolite and shungite was studied. Oxidation rate of sulfide minerals was estimated by the decrease of Fe3+ (oxidant) and increase of Fe2+ ions in the solution. It was revealed that chemical oxidation of chalcopyrite by biogenic ferric iron occu...
Autori: Arevik Vardanyan
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27563

This work describes the application of Fenton’s like system (H2O2/Cu2+) assisted by microwaves to the removal of phenolic compounds from olive mill wastewater (OMWs). The effect of various operating conditions, namely copper ion concentrations (X1), hydrogen peroxide (X2), time of irradiation (X3) and microwave power (X4) were evaluated by factorial design of experiments. Results showed that X1, X2, X3 and X4 had significant effects on the response followed by the interactions X1X2, X1X3, ...
Autori: Hamida Iboukhoulef
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27602

The study of binary biosorption of Pb(II) and Cu(II) was performed by pine nuts shell. Results were compared with the single biosorption of Pb(II) and the single biosorption of the Cu(II). Experiments were performed in batch stirred and in a continuous system. The presence of lead caused a slightly decrease of the copper biosorption yield and can be related to the copper equilibrium uptake. This antagonistic action can be related to competition phenomena between metal ions in solution for active...
Autori: Gabriel Blázquez
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27611

A 120 kilometers reach of the Prut River, Romania was surveyed and the concentrations of four trace metals (copper, cadmium, lead and zinc) were determined in water and sediments. These elements are the main pollutants expected in the region, as a steel-producing factory in Romania is located in the close neighborhood of an area under protection, the Lower Prut Floodplain Natural Park. Samples were collected in 2010 and 2011 from the water-sediment interface at six locations along the lower sect...
Autori: Marius Lucian Matache
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27612

Pyrometallurgical recycling of lead from spent batteries entails secondary waste fractions generated in the blast furnace as iron stone and lead slags. For further purification of both fractions, hydrometallurgic processing is proposed. This paper focuses on purification of iron stone, in view of recovering metals (mainly lead) and of producing decontaminated iron stone fit for further recycling. The results demonstrate that iron stone is mainly composed of iron and lead; copper, zinc and antimo...
Autori: Bart Van der Bruggen
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27642

Copper pollution is common across the world and has caused serious public health problems recently. Among the conventional methods, adsorption has proved effective, economic, versatile and simple for the removal of aqueous Cu(II) contaminants. Deposits of natural Kaolin are abundant around the world, and are regarded as valueless due to its limited usage in industry. In this study, the adsorption behavior of natural Kaolin towards Cu(II) was evaluated. According to the results, the isothermal ad...
Autori: Qiang Tang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27651

The Silicon wafer plays an important role in modern electronic products. During the production of Silicon wafer, a large amount of scrap Silicon wafer is generated. The necessity for it to be recycled and recovered is of vast importance since the metal Silicon (Si) is the major by product. Besides Silicon, the wafers also contain a small quantity of Copper (Cu) and Aluminum (Al), that are considered as minor elements during the recovery process of the Silicon wafer production. Therefore, in o...
Autori: Ching-Hwa Lee
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27660

In this study, the removal of Cu(II) from real industrial wastewater, being taken from galvanotechnic industry, by means of manganese ferrite (MnFe2O4) nanoparticles (NPs) was investigated. The effects of pH, adsorbent dosage, and contact time on Cu(II) removal from wastewater were monitored using the real wastewater while the effect of initial concentration was studied on synthetic aqueous solutions. Optimal conditions were found for copper removal in this study. Cu(II) removal and adsorption c...
Autori: Naim Sezgin
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27743

Within this study a total content of 20 elements was determined in 25 soil samples taken from the vicinity of the "Buchim" mine, Republic of Macedonia, covering an area of 14.2 km2. The results have been compared to new Dutchlist and NOAA standards and it was concluded that the content of As, Cd, Cu, Pb and Zn in most of the samples is over the corresponding optimal or action values probably due to the anthropogenic activities. Thus As values ranged 13.1-225 mg kg-1 with 20 above the o...
Autori: Todor Serafimovski
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27844

The catalytic hydrogenolysis of glycerol, a by-product of the biodiesel manufacturing process was studied on copper chromite catalysts with different chemical composition. The obtaining of propylene glycol was studied under mild reaction conditions (180- 240oC temperature range, 8 hours reaction time and moderate pressures). These important parameters have significant effects on the glycerol conversion and that is way the actual study was concerned to the obtaining of a superior selectivity t...
Autori: Adriana Marinoiu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27892

Biosorption of copper(II) by lyophilized and thermally treated bacterial biomass of Pseudomonas aeruginosa PAO1 and Pseudomonas fluorescens BME in aqueous suspension was studied. The cell surface properties were characterized and the experimental conditions, e.g., pH, adsorption time, and initial metal concentration were optimized for efficient biosorption. The surface charge was negative at pH above 2.5 for P. aeruginosa, and above pH 4 for P. fluorescens. The highest copper(II) uptake was ...
Autori: Anikó Kőnig-Péter
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27917

Chlortetracycline (CTC) and copper (Cu) are simultaneously used as feed additives to improve the growth performance and to prevent infection in pig farming. After ingestion by animals, most of these compounds are excreted and coexist in swine manure. They might have an influence on anaerobic digestion when the swine manure is used as substrate in a biogas plant. The purpose of this study was to investigate the effects of both CTC and Cu on batch swine manure anaerobic digestion in order to bette...
Autori: Rui Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=27983

Trace elements (TEs) in contaminated soils are considered as primary jeopardy issues in developing countries which can cause major concerns for this industry and also menace the surrounding ecosystems, human health and wildlife, so urgent reclamation methods are required. The present research aims to evaluate potential phytoremediation capability of selected plant species Tamarix Spp., Haloxylon Spp. and Malcolmia Africana to grow in TE contaminated soils. Muteh Gold mine, a widespread mountaino...
Autori: Ali Daryabeigi Zand
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28056

Wastewater generated from industrial activities has delivered elevated heavy metal concentrations into fresh and salted aqueous systems. Herein, the migrated trace metals were studied from their initial location through a coastal aquifer up to the seawater. The experiments were carried out at lab scale using a sandbox with glass beads and two attached chambers containing natural groundwater and seawater. The study focused on the transport behaviour of heavy metals such as copper, zinc and lead i...
Autori: Abdelkader Tawfeek Ahmed
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28111

Arsenic-containing acid wastewater produced in the mining and smelting process will bring great harm to the environment, while to treat arsenic-containing wastewater with iron salt and lime is an economical and effective method. In this paper, iron salt was added to co-precipitate the arsenic and heavy metals, the pH value of arsenic containing acid leaching solution was adjusted by adding of lime. The stability of co-precipitates was also investigated in this study. The results show that the ir...
Autori: Yongliang Wang
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28121

Copper and Zinc co-doped titania nano photocatalyst (Cu-Zn-TiO2 NPC) was fabricated and characterized using room temperature X-ray diffraction (XRD), field emission electron microscopy (FESEM) with high-resolution transmission electron microscopy (HRTEM) and energy dispersion X-ray (EDX). X-ray diffraction studies of the Cu2+-Zn2+/TiO2 show the presence of anatase phase TiO2 and in the sample prepared from 0.05, 0.10, 0.15 and 0.20 mmol have also shown the presence of anatase phase only. The ph...
Autori: Tentu Nageswara Rao
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28198

Even though carbonate fraction of soils significantly influences soil contaminant retention, there are few reports in the literature on the influence of temperature on contaminant retention of carbonated soils. Therefore, this study was conducted to investigate the effect of temperature on buffering capacity in carbonated and decarbonated kaolinite and on changes in intensity of x-ray diffraction for major peak of kaolinite. To achieve this aim, samples of kaolinite containing 2.5% carbonate and...
Autori: Vahid Reza Ouhadi
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28231

Pollution with aromatic hydrocarbon has been rising because of the extreme usage of benzene containing compounds. Most of the people, animals and plants have been exposed to aromatic hydrocarbons due to polluted water sources. The aim of the present work was to carry out an experimental study for the photocatalytic degradation of aromatic hydrocarbon containing compounds by irontitanium- pillared interlayered clays (Fe-Ti-PILCs) and copper-titanium-pillared interlayered clays (Cu-Ti-PILCs). For ...
Autori: Beytullah Eren
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28249

Growth of city population and migration of communities lead to higher accumulation of heavy metals in coastal areas of the Caspian Sea suburbs. In the present study there are represented geographical and ecological locations and environmental monitoring results of the Caspian Sea offshore and coastal area near Akshukyr (Aktau suburbs). The shallow offshore near Aktau city and adjacent areas were monitored in cooperation with the Institute of Ocean Sciences. Sea water analysis carried out specia...
Autori: Nurgul Janaliyeva
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28263

The treatment of acidic wastewater of copper sulfide produces a huge amount of sediment, which can be processed into the planting matrix for ecological restoration of mines. This paper attempts to screen out the plants suitable for the acidic wastewater sediment, laying the basis for ecological restoration of mines. Therefore, 14 plant species were selected for preliminary tests on survival rate and growth tests in sediment pond. The survival rates and growth conditions of each plant species in...
Autori: Jinchun Xue
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28268

The concentrations of Copper (Cu), cadmium (Cd), manganese (Mn) and lead (Pb) in liver, kidneys and red meat of cattle slaughtered in selected abattoirs in Owerri metropolis, Nigeria were studied using atomic absorption spectroscopy (AAS). This was performed in relation to their concentrations in a forage grass, Panicum maximum randomly harvested from roadsides of Owerri- Onitsha and Owerri-Aba expressways. Results obtained showed that cattle meat samples contained all heavy metals studied. Thei...
Autori: Henry Uzoma Anuforo
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28320

The study presents the experimental testing of a heat exchanger with uniform thermal flux (HEUTF), used as a cold source in HVAC systems with heat pumps. A water-water heat exchanger is tested, having a special geometry, with uniform thermal flux along the system. The heat exchanger proposed consists of a distributor and a collector, connected to each other by means of 20 staggered copper pipes, being suitable for serving low or medium geothermal sources. The innovation consists in the uniformit...
Autori: Sebastian Valeriu Hudișteanu
ISSN: 1843 - 3707
http://www.ecozone.ro/reviste.php?RID=28340